Printing of stoneware
A Dictionary of Arts, Manufactures and Mines · 1840 · p. 1028
—The printing under the stoneware glaze is generally performed by means of cobalt, and has different shades of blue according to the quantity of colouring matter employed. After having subjected this oxide to the proce es requisite for its purification, it is mixed with a certain quantity of ground flints and sulphate of baryta, proportioned to the dilution of the shade. These materials are fritted and ground; but before they are used, they must be mixed with a flux consisting of equal parts by weight of flint gla and ground flints, which serves to fix the colour upon the biscuit, so that the immersion in the glaze liquor may not displace the lines printed on, as also to aid in fluxing the cobalt. The following are the proce es usually practised in Staff ords hire for printing under the glaze. The cobalt, or whatever colour is employed, should be ground upon a porphyry slab, with a varnish prepared as follows:—A pint of linseed oil is to be boiled to the consistence of thick honey, along with 4 ounces of rosin, half a pound of tar, and half a pint of oil of amber. This is very tenacious, and can be used only when liquefied by heat; which the printer effects by spreading it upon a hot cast-iron plate. The printing plates are made of copper, engraved with pretty deep lines in the common way. The printer, with a leather muller, spreads upon the engraved plate, previously heated, his colour, mixed up with the above oil varnish, and removes what is superfluous with a pallet knife; then cleans the plate with a do il filled with bran, tapping and wiping as if he were removing dust from it. This operation being finished, he takes the paper intended to receive the impre ion, soaks it with soap-water, and lays it moist upon the copper-plate. The soap makes the paper part more readily from the copper, and the thick ink part more readily from the biscuit. The copper-plate is now pa ed through the engraver’s cylinder pre , the proof leaf is lifted off and handed to the women, who cut it into detached pieces, which they apply to the surface of the biscuit. The paper best fitted for this purpose is made entirely of linen rags; it is very thin, of a yellow colour, and unsized, like ti ue blotting-paper. The stoneware biscuit never receives any preparation before being imprinted, the oil of the colour being of such a nature as to fix the figures firmly. The printed paper is pre ed and rubbed on with a roll of flannel, about an inch and a half in diameter, and 12 or 15 inches long, bound round with twine, like a roll of tobacco. This is used as a burnisher, one end of it being rested against the shoulder, and the other end being rubbed upon the paper; by which means it transfers all the engraved traces to the biscuit. The piece of biscuit is laid aside for a little, in order that the colour may take fast hold; it is then plunged into water, and the paper is washed away with a sponge. When the paper is detached, the piece of ware is dipped into a caustic alkaline lye to saponify the oil, after which it is immersed in the glaze liquor, with which the printed figures readily adhere. This proce , which is easy to execute, and very economical, is much preferable to the old plan of pa ing the biscuit into the muffle after it had been printed, for the purpose of fixing and volatilizing the oils. When the paper impre ion is applied to pieces of porcelain, they are heated before being dipped in the water, because, being already semi-vitrified, the paper sticks more closely to them than to the biscuit, and can be removed only by a hard brush. The impre ion above the glaze is done by quite a different proce , which dispenses with the use of the pre . A quantity of fine clean glue is melted and poured hot upon a large flat dish, so as to form a layer about a quarter of an inch thick, and of the consistence of jelly. When cold it is divided into cakes of the size of the copper-plates it is intended to cover. The operative (a woman) rubs the engraved copper-plate gently over with linseed oil boiled thick, immediately after which she applies the cake of glue, which she pre es down with a silk do il filled with bran. The cake licks up all the oil out of the engraved lines; it is then cautiously lifted off, and transferred to the surface of the glazed ware which it is intended to print. The glue cake being removed, the enamel surface must be rubbed with a little cotton, whereby the metallic colours are attached only on the lines charged with oil; the piece is then heated under the muffle. The same cake of glue may serve for several impre ions.
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