Polarization

The Standart Electrical Dictionary · 1892 · p. 6
(a) The depriving of a voltaic cell of its proper electro-motive force. Polarization may be due to various causes. The solution may become exhausted, as in a Smee battery, when the acid is saturated with zinc and thus a species of polarization follows. But the best definition of polarization restricts it to the development of counter-electro-motive force in the battery by the accumulation of hydrogen on the negative (carbon or copper) plate. To overcome this difficulty many methods are employed. Oxidizing solutions or solids are used, such as solution of chromic acid or powdered manganese dioxide, as in the Bunsen and Leclanché batteries respectively; a roughened surface of platinum black is used, as in the Smee battery; air is blown through the solution to carry off the hydrogen, or the plates themselves are moved about in the solution. (b) Imparting magnetization to a bar of iron or steel, thus making a permanent magnet, is the polarization of the steel of which it is made. Polarization may be permanent, as in steel, or only temporary, as in soft iron. (c) The strain upon a dielectric when it separates two oppositely charged surfaces. The secondary discharge of a Leyden jar, and its alteration in volume testify to the strain put upon it by charging. (d) The alteration of arrangement of the molecules of an electrolyte by a decomposing current. All the molecules are supposed to be arranged with like ends pointing in the same direction, positive ends facing the positively-charged plate and negative ends the negatively-charged one. (e) The production of counter-electro-motive force in a secondary battery, or in any combination capable of acting as the seat of such counter-electro-motive force. (See Battery, Secondary--Battery, Gas.) The same can be found often in organized cellular ti ue such as that of muscles, nerves, or of plants. If a current is pa ed through this in one direction, it often establishes a polarization or potential difference that is susceptible of giving a return current in the opposite direction when the charging battery is replaced by a conductor.
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