SALTS
A Dictionary of Arts, Manufactures and Mines · 1840 · p. 1098
are an important cla of chemical compounds, antiently studied under the Greek title of Halurgy . At one period every inorganic substance readily soluble in water, was regarded as a salt; and afterwards, every substance soluble in five hundred times its weight of water. Thus both acid and alkaline bodies came to be enrolled among salts; but latterly, the combinations of the acids with alkalis, earths, and metallic calces (now styled oxides), were alone thought to be entitled to the denomination of salts, in consequence of their resemblance in appearance, and supposed analogy in composition, to culinary salt. Since Sir H. Davy demonstrated that this substance contained neither acid nor alkaline matter, but that it consisted of chlorine and the metal sodium, the generality of chemists found it impo ible to include salts under one category of constitution; while a few have rashly offered to cut the knot, by excluding from the saline family, chloride of sodium, the patriarch of the whole. Salts , may be justly divided into three orders: 1. The binary, consisting of two single members; such as the bromides, chlorides, cyanides, fluorides, iodides, carburets, phosphurets, sulphurets, . 2. The bi-binary, consisting of two double members; such as the borates, bromates, carbonates, chlorates, sulphates, sulphites, hyposulphites, sulphohydrates, . 3. The ternary, consisting of two single members of one genus, and one member of another; such as the boro-fluorides, silico-fluorides, sulpho-cyanides, chloriodides, . The species of each order may exist in three states, constituting neutral salts; supersalts; and subsalts; as for example, the chloride of sodium, the bisulphate of pota a, the sub nitrate of lead, . In the above arrangement, cyanogen is allowed to represent a simple substance, from its forming analogous compounds with chlorine and iodine. The neutral state of salts is commonly indicated by their solutions not changing the colours of litmus, violets, or red cabbage; the sub-state of salts, by their turning the violet and cabbage green; and the super-state of salts, by their changing the purple of litmus, violets, and cabbage, red; but to the generality of this criterion there are some exceptions. The atomic theory may be advantageously resorted to, in this predicament. 1. When one prime equivalent of the one member (whether single or double) of a salt, combines with one prime of the other member, a neutral salt is the result, as in chloride of sodium or nitrate of pota a. 2. When two primes of the electro-negative member combine with one prime of the electro-positive, a supersalt is formed, as bichloride of tin, or bisulphate of pota a. 3. When one prime of the electro-negative member combines with two or more primes of the electro-positive, a subsalt is produced, as the subacetate and sub chromate of lead, .
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