Red Enamel
A Dictionary of Arts, Manufactures and Mines · 1840 · p. 446
—We have just stated, that protoxide of copper afforded a fine colour when it could be fixed, a result difficult to obtain on account of the fugitive nature of this oxide; slight variations of temperature enabling it to absorb more oxygen. The proper point of fusion must be seized, for taking it from the fire whenever the desired colour is brought out. Indeed, when a high temperature has produced peroxidize ment, this may be corrected by adding some combustible matter, as charcoal, tallow, tartar, . The copper then returns to its minimum of oxidize ment, and the red colour which had vanished, reappears. It is po ible, in this way, and by pushing the heat a little, to accomplish the complete reduction of a part of the oxide; and the particles of metallic copper thereby di eminated in a reddish ground, give this enamel the aspect of the stone called avanturine . The surest and easiest method of procuring protoxide of copper is to boil a solution of equal parts of sugar, and sulphate or rather acetate of copper, in four parts of water. The sugar takes po e ion of a portion of the oxygen of the cupreous oxide, and reduces it to the protoxide; when it may be precipitated in the form of a granular powder of a brilliant red. After about two hours of moderate ebullition, the liquid is set aside to settle, decanted off the precipitate, which is washed and dried. This pure oxide, properly employed by itself, furnishes a red which vies with the finest carmine, and by its means every tint may be obtained from red to orange, by adding a greater or smaller quantity of peroxide of iron. The preparations of gold, and particularly the oxide and purple of Ca ius, are likewise employed, with advantage, to colour enamel red, and this composition resists a powerful fire tolerably well. For some time back, solutions of gold, silver, and platinum have been used with succe instead of their oxides; and, in this way, a more intimate mixture may be procured, and, consequently, more homogeneous tints.
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