Yellow Enamel

—There are many proce es for making this colour in enamel; but it is somewhat difficult to fix, and it is rarely obtained of an uniform and fine tint. It may be produced directly with some preparations of silver, as the phosphate or sulphate; but this method does not always succeed, for too strong a heat or powerful fluxes readily destroy it, and nitre is particularly prejudicial. This uncertainty of succe with the salts of silver causes them to be seldom employed; and oxides of lead and antimony are therefore preferred, which afford a fine yellow when combined with some oxides that are refractory enough to prevent their complete vitrification. One part of white oxide of antimony may be taken with from one to three parts of white lead, one of alum, and one of sal-ammoniac. Each of these substances is to be pulverized, and then all are to be exactly mixed, and exposed to a heat adequate to decompose the sal-ammoniac. This operation is judged to be finished when the yellow colour is well brought out. There is produced here a combination quite analogous to that known under the name of Naples yellow. Other shades of yellow may be procured either with the oxide of lead alone, or by adding to it a little red oxide of iron; the tints varying with the proportion of the latter. Clouet says, in his memoir on enamels, that a fine yellow is obtained with pure oxide of silver, and that it is merely nece ary to spread a thin coat of it on the spot to be coloured. The piece is then exposed to a moderate heat, and withdrawn as soon as this has reached the proper point. The thin film of metallic silver revived on the surface being removed, the place under it will be found tinged of a fine yellow, of hardly any thickne . As the pellicle of silver has to be removed which covers the colour, it is requisite to avoid fixing this film with fluxes; and it ought therefore to be applied after the fusion of the rest. The yellows require in general little flux, and they answer better with one of a metallic nature.