PARAFFINE
A Dictionary of Arts, Manufactures and Mines · 1840 · p. 953
Distil beech-tar to dryne , rectify the heavy oil which collects at the bottom of the receiver, and when a thick matter begins to rise, set aside what is distilled, and urge the heat moderately as long as any thing more distils. Pyrélaine pa es over, containing crystalline scales of paraffine. This mixture being digested with its own volume of alcohol of 0·833, forms a limpid solution, which is to be gradually diluted with more alcohol, till its bulk becomes 6 or 8 times greater. The alcohol, which at first di olves the whole, lets the paraffine gradually fall. The precipitate being washed with cold alcohol till it becomes nearly colourle , and then di olved in boiling alcohol, is deposited on cooling in minute spangles and needles of pure paraffine. Or the above mixture may be mixed with from 1 ⁄ 4 to 1 ⁄ 2 its weight of concentrated sulphuric acid, and subjected for 12 hours to digestion, at a heat of 150° F., till, on cooling, crystals of paraffine appear upon the surface. These are to be washed with water, di olved in hot alcohol, and crystallized. Paraffine is a white substance, void of taste and smell, feels soft between the fingers, has a specific gravity of 0·87, melts at 112° Fahr., boils at a higher temperature with the exhalation of white fumes, is not decomposed by dry distillation, burns with a clear white flame without smoke or residuum, does not stain paper, and consists of 85·22 carbon, and 14·78 hydrogen; having the same composition as olefiant gas. It is decomposed neither by chlorine, strong acids, alkalis, nor pota ium; and unites by fusion with sulphur, phosphorus, wax, and rosin. It di olves readily in warm fat oils, in cold e ential oils, in ether, but sparingly in boiling absolute alcohol. Paraffine is a singular solid bicarburet of hydrogen; it has not hitherto been applied to any use, but it would form admirable candles.
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