Tender

porcelain, styled also vitreous porcelain, has no relation with the preceding in its composition; it always consists of a vitreous frit, rendered opaque and le fusible by the addition of a calcareous or marly clay. Its glaze is an artificial gla or crystal, into which silica, alkalis, and lead enter. This porcelain has a more vitreous biscuit, more transparent, a little le hard, and le fragile, but much more fusible than that of the hard porcelain. Its glaze is more glo y, more transparent, a little le white, much tenderer, and more fusible. The biscuit of the hard porcelain made at the French national manufactory of Sèvres is generally composed of a kaolin clay, and of a decomposed felspar rock; analogous to the china clay of Cornwall, and Cornish stone. Both of the above French materials come from Saint Yriex-la-perche, near Limoges. After many experiments, the following composition has been adopted for the service paste of the royal manufactory of Sèvres; that is, for all the ware which is to be glazed: silica, 59; alumina, 35·2; potash, 2·2; lime, 3·3. The conditions of such a compound are pretty nearly fulfilled by taking from 63 to 70 of the washed kaolin or china clay, 22 to 15 of the felspar; nearly 10 of flint powder, and about 5 of chalk. The glaze is composed solely of solid felspar, calcined, crushed, and then ground fine at the mill. This rock pretty uniformly consists of silica 73, alumina 16·2, potash 8·4, and water 0·6. The kaolin is washed at the pit, and sent in this state to Sèvres, under the name of decanted earth . At the manufactory it is washed and elutriated with care; and its slip is pa ed through fine sieves. This forms the plastic, infusible, and opaque ingredient to which the substance must be added which gives it a certain degree of fusibility and semi-transparency. The felspar rock used for this purpose, should contain neither dark mica nor iron, either as an oxide or sulphuret. It is calcined to make it crushable, under stamp-pestles driven by machinery, then ground fine in hornstone mills, as represented in figs. 897 , 898 , 899 , and 900. This pulverulent matter being diffused through water, is mixed in certain proportions, regulated by its quality, with the argillaceous slip . The mixture is deprived of the chief part of its water in shallow plaster pans without heat; and the resulting paste is set aside to ripen, in damp cellars, for many months. When wanted for use, it is placed in hemispherical pans of plaster, which absorb the redundant moisture; after which it is divided into small lumps, and completely dried. It is next pulverized, moistened a little, and laid on a floor, and trodden upon by a workman marching over it with bare feet in every direction; the parings and fragments of soft moulded articles being intermixed, which improve the plasticity of the whole. When sufficiently tramped, it is made up into ma es of the size of a man’s head, and kept damp till required. The dough is now in a state fit for the potter’s lathe; but it is much le plastic than stoneware paste, and is more difficult to fashion into the various articles; and hence one cause of the higher price of porcelain. The round plates and dishes are shaped on plaster moulds; but sometimes the paste is laid on as a crust, and at others it is turned into shape on the lathe. When a crust is to be made, a moistened sheep-skin is spread on a marble table; and over this the dough is extended with a rolling pin, supported on two guide-rules. The crust is then transferred over the plaster mould, by lifting it upon the skin; for it wants tenacity to bear raising by itself. When the piece is to be fashioned on the lathe, a lump of the dough is thrown on the centre of the horizontal wooden disc, and turned into form as directed in treating of stoneware, only it must be left much thicker than in its finished state. After it dries to a certain degree on the plaster mould, the workman replaces it on the lathe, by moistening it on its base with a wet sponge, and finishes its form with an iron tool. A good workman at Sèvres makes no more than from 15 to 20 porcelain plates in a day; whereas an English potter, with two boys, makes from 1000 to 1200 plates of stoneware in the same time. The pieces which are not round, are shaped in plaster moulds, and finished by hand. When the articles are very large, as wash-hand basins, salads, ., a flat cake is spread above a skin on the marble slab, which is then applied to the mould with the sponge, as for plates; and they are finished by hand. The projecting pieces, such as handles, beaks, spouts, and ornaments, are moulded and adjusted separately; and are cemented to the bodies of china-ware with slip, or porcelain dough thinned with water. In fact, the mechanical proce es with porcelain and the finer stoneware are substantially the same; only they require more time and greater nicety. The least defect in the fabrication, the smallest bit added, an unequal pre ure, the cracks of the moulds, although well repaired, and seemingly effaced in the clay shape, re-appear after it is baked. The articles should be allowed to dry very slowly; if hurried but a little, they are liable to be spoiled. When quite dry, they are taken to the kiln. The kiln for hard porcelain at Sèvres, is a kind of tower in two flats, constructed of fire-bricks; and resembles, in other respects, the stoneware kiln already figured and described. The fuel is young asp in wood, very dry, and cleft very small; it is put into the apertures of the four outside furnaces or fire-mouths, which discharge their flame into the inside of the kiln; each floor being closed in above, by a dome pierced with holes. The whole is covered in by a roof with an open pa age, placed at a proper distance from the uppermost dome. There is, therefore, no chimney proper so called. See Stone, artificial . The raw pieces are put into the upper floor of the kiln; where they receive a heat of about the 60th degree of Wedge wood’s pyrometer, and a commencement of baking, which, without altering their shape, or causing a perceptible shrinking of their bulk, makes them completely dry, and gives them sufficient solidity to bear handling. By this preliminary baking, the clay loses its property of forming a paste with water; and the pieces become fit for receiving the glazing coat, as they may be dipped in water without risk of breakage. The glaze of hard porcelain is a felspar rock: this being ground to a very fine powder, is worked into a paste with water mingled with a little vinegar. All the articles are dipped into this milky liquid for an instant; and as they are very porous, they absorb the water greedily, whereby a layer of the felspar glaze is deposited on their surface, in a nearly dry state, as soon as they are lifted out. Glaze-pap is afterwards applied with a hair brush to the projecting edges, or any points where it had not taken; and the powder is then removed from the part on which the article is to stand, lest it should get fixed to its support in the fire. After these operations it is replaced in the kiln, to be completely baked. The articles are put into saggers, like those of fine stoneware; and this operation is one of the most delicate and expensive in the manufacture of porcelain. The saggers are made of the plastic or potter’s clay of Abondant, to which about a third part of cement of broken saggers has been added. As the porcelain pieces soften somewhat in the fire, they cannot be set above each other, even were they free from glaze; for the same reason, they cannot be baked on tripods, several of them being in one case, as is done with stoneware. Every piece of porcelain requires a sagger for itself. They must, moreover, be placed on a perfectly flat surface, because in softening they would be apt to conform to the irregularities of a rough one. When therefore any piece, a soup plate for example, is to be saggered , there is laid on the bottom of the case a perfectly true disc or round cake of stoneware, made of the sagger material, and it is secured in its place on three small props of a clay-lute, consisting of potter’s clay mixed with a great deal of sand. When the cake is carefully levelled, it is moistened, and dusted over with sand, or coated with a film of fire-clay slip, and the porcelain is carefully set on it. The sand or fire-clay hinders it from sticking to the cake. Several small articles may be set on the same cake, provided they do not touch one another. The saggers containing the pieces thus arranged, are piled up in the kiln over each other, in the columnar form, till the whole space be occupied; leaving very moderate intervals between the columns to favour the draught of the fires. The whole being arranged with these precautions, and several others, too minute to be specified here, the door of the kiln is built up with 3 rows of bricks, leaving merely an opening 8 inches square, through which there is acce to a sagger with the nearest side cut off. In this sagger are put fragments of porcelain intended to be withdrawn from time to time, in order to judge of the progre of the baking. These are called time-pieces or watches ( montres ). This opening into the watches is closed by a stopper of stoneware. The firing begins by throwing into the furnace-mouths some pretty large pieces of white wood, and the heat is maintained for about 15 hours, gradually raising it by the addition of a larger quantity of the wood, till at the end of that period the kiln has a cherry-red colour within. The heat is now greatly increased by the operation termed covering the fire . Instead of throwing billets vertically into the four furnaces, there is placed horizontally on the openings of these furnaces, asp in wood of a sound texture, cleft small, laid in a sloping position. The brisk and long flame which it yields dips into the tunnels, penetrates the kiln, and circulates round the sagger-piles. The heat augments rapidly, and, at the end of 13 or 15 hours of this firing, the interior of the kiln is so white, that the watches can hardly be distinguished. The draught, indeed, is so rapid at this time, that one may place his hand on the slope of the wood without feeling incommoded by the heat. Every thing is consumed, no small charcoal remains, smoke is no longer produced, and even the wood-ash is di ipated. It is obvious that the kiln and the saggers must be composed of a very refractory clay, in order to resist such a fire. The heat in the Sèvres kilns mounts so high as the 134th degree of Wedge wood. At the end of 15 or 20 hours of the great fire; that is, after from 30 to 36 hours’ firing, the porcelain is baked; as is ascertained by taking out and examining the watches. The kiln is suffered to cool during 3 or 4 days, and is then opened and discharged. The sand strewed on the cakes to prevent the adhesion of the articles to them, gets attached to their sole, and is removed by friction with a hard sandstone; an operation which one woman can perform for a whole kiln in le than 10 days; and is the last applied to hard porcelain, unle it needs to be returned into the hot kiln to have some defects repaired. The materials of fine porcelain are very rare; and there would be no advantage in making a gray-white porcelain with coarser and somewhat cheaper materials, for the other sources of expense above detailed, and which are of most consequence, would still exist; while the porcelain, losing much of its brightne , would lose the main part of its value. Its pap or dough, which requires tedious grinding and manipulation, is also more difficult to work into shapes, in the ratio of 80 to 1, compared to fine stoneware. Each porcelain plate requires a separate sagger; so that 12 occupy in the kiln a space sufficient for at least 38 stoneware plates. The temperature of a hard porcelain kiln being very high, involves a proportionate consumption of fuel and waste of saggers. With 40 steres (cubic metres) of wood, 12,000 stoneware plates may be completely fired, both in the biscuit and glaze kilns; while the same quantity of wood would bake at most only 1000 plates of porcelain. To these causes of high price, which are constant and e ential, we ought to add the numerous accidents to which porcelain is exposed at every step of its preparation, and particularly in the kiln; these accidents damage upwards of one-third of the pieces, and frequently more, when articles of singular form and large dimensions are adventured. The best English porcelain is made from a mixture of the Cornish kaolin (called china clay), ground flints, ground Cornish stone, and calcined bones in powder, or bone-ash, besides some other materials, according to the fancy of the manufacturers. A liquid pap is made with these materials, compounded in certain proportions, and diluted with water. The fluid part is then withdrawn by the absorbent action of dry stucco basins or pans. The dough, brought to a proper stiffne , and perfectly worked and kneaded on the principles detailed above, is fashioned on the lathe, by the hands of modellers, or by pre ure in moulds. The pieces are then baked to the state of biscuit in a kiln, being enclosed, of course, in saggers. This biscuit has the aspect of white sugar, and being very porous, must receive a vitreous coating. The glaze consists of ground felspar or Cornish stone. Into this, diffused in water, along with a little flint-powder and potash, the biscuit ware is dipped, as already described, under stoneware. The pieces are then fired in the glaze-kiln, care being taken, before putting them into their saggers, to remove the glaze powder from their bottom parts, to prevent their adhesion to the fire-clay ve el. TENDER PORCELAIN. Tender porcelain, or soft china-ware, is made with a vitreous frit, rendered le fusible and opaque by an addition of white marl or bone-ash. The frit is, therefore, first prepared. This, at Sèvres, is a composition, made with some nitre, a little sea salt, Alicant barilla, alum, gypsum, and much siliceous sand or ground flints. That mixture is subjected to an incipient pasty fusion in a furnace, where it is stirred about to blend the materials well; and thus a very white spongy frit is obtained. It is pulverized, and to every three parts of it, one of the white marl of Argenteuil is added; and when the whole are well ground, and intimately mixed, the paste of tender porcelain is formed. As this paste has no tenacity, it cannot bear working till a mucilage of gum or black soap be added, which gives it a kind of plasticity, though even then it will not bear the lathe. Hence it must be fashioned in the pre , between two moulds of plaster. The pieces are left thicker than they should be; and when dried, are finished on the lathe with iron tools. In this state they are baked, without any glaze being applied; but as this porcelain softens far more during the baking than the hard porcelain, it needs to be supported on every side. This is done by baking on earthen moulds all such pieces as can be treated in this way, namely plates, saucers, . The pieces are reversed on these moulds, and undergo their shrinkage without losing their form. Beneath other articles, supports of a like paste are laid, which suffer in baking the same contraction as the articles, and of course can serve only once. In this operation saggers are used, in which the pieces and their supports are fired. The kiln for the tender porcelain at Sèvres is absolutely similar to that for the common stoneware; but it has two floors; and while the biscuit is baked in the lower story, the glaze is fused in the upper one; which causes considerable economy of fuel. The glaze of soft porcelain is a species of gla or crystal prepared on purpose. It is composed of flint, siliceous sand, a little potash or soda, and about two-fifth parts of lead oxide. This mixture is melted in crucibles or pots beneath the kiln. The resulting gla is ground fine, and diffused through water mixed with a little vinegar to the consistence of cream. All the pieces of biscuit are covered with this glazy matter, by pouring this slip over them, since their substance is not absorbent enough to take it on by immersion. The pieces are encased once more each in a separate sagger, but without any supports; for the heat of the upper floor of the kiln, though adequate to melt the glaze, is not strong enough to soften the biscuit. But as this first vitreous coat is not very equal, a second one is applied, and the pieces are returned to the kiln for the third time. See Stone, artificial , for a view of this kiln. The manufacture of soft porcelain is longer and more difficult than that of hard; its biscuit is dearer, although the raw materials may be found every where; and it furnishes also more refuse. Many of the pieces split asunder, receive fi ures, or become deformed in the biscuit-kiln, in spite of the supports; and this vitreous porcelain, moreover, is always yellower, more transparent, and incapable of bearing rapid transitions of temperature, so that even the heat of boiling water frequently cracks it. It po e es some advantages as to painting, and may be made so gaudy and brilliant in its decorations, as to captivate the vulgar eye.