ALLYL

n. A?li°1. For deriv., see ALLIVM and -yl.* _ Lat., allylum. Fr., allyle. Ger. Allyl. It., allile. Sp., alilo. Syn. acryl, propylenyl. A univalent radicle of the composition Calls CH,: CH.CH',, differing from the trivalent radicle glyceryl, CH’, — CH’ — CH’s, in the double linking of its first 2 carbon atoms. Its compounds occur in oil of garlic and oil of mustard. A. in the free state always occurs as a double molecule. [B, 2, 4.] See DIALLYL. —Acid a. salphate. See A. sulphate, —. See ETHYL allyl ace to acetate. —A. acetate. Fr., acétate d’allyle, Ger., E igsture-Allyl ester. A liquid of the constitution CHz.CO.0(C,Hg) = CsHgO,. [B, 4.]—. Fr., allyl-acétate. Ger., ally les sig sau res Salz. A salt of allyl-acetic acid. (B.)-A’a tic aeld. Fr., acide allyl-acétique. Ger., Allyle igsäure. It., acido allil-acetico. Sp., âcido alil-acético. A colorle oily liquid having the properties of a monobasic acid and the constitution CyHg0, = )—CO.OH, or that of acetic acid in which allyl replaces hydrogen. It is isomeric with tiglic and angelic acids. [B,4.|—A’acetic ether. Fr., éther allylacétique. Ger., Allyle igsdure-Fster. It.. etere allil-acetico. Au allyl acetate of a compound radicle, usually applied to ethyl a.-e. (etl vd allyl acetate), [B, 2.J—A’ace to acetate. An ace to acetate in which a. replaces the radicle hydrogen. [B.} See Ernyt allyl ace to acetate,—A. acetone. See METHYLISOCROTYL KETONE.—A. alcohol. Fr., alcool eae Ger., Allylalkohol. It., alcool allilico. A mobile liquid of pungent odor prepared by the action of oxalic acid upon glycerin and having the constitution C,H,0 = CH,: CH-CH,.OH, isomeric with propionic aldehyde. [B, 3, 4.]— A. alcohol bromide, A. alcoho] chloride, À. alcohol cyanide. Fr., bromure d'alcool allylique, chlorure d'atcool altylique, eyanure d’alcool artic, Ger., Allylalkolbromür, Allylalkoholchlorür, Allylalkoholcyanür. Addition compounds of a. with chlorine, bromine, and cyanogen, See A. alcohol dibromide, A. alcohol dichloride, A. alcohol dicyanide.—A. alcohol romide. Fr., dibromure alcool allylique, alcool allylique bibromé. Ger., Allyl alkoholdibromii See DiproMHvDRIN.—A. alcohol dichloride. Fr., dichlorure d'alcool allylique, alcool allylique bichlore. Ger., Allyl alko hold ich lorür. See DICHLORHYDRIN.—Â. alcohol dicyanide. Fr., dicyanure d’alcool all i(liquz. Ger., Allyl alko hold i cyanür. See Dicyannyprin,—A. aldehyde. Acrolein. [L, 65.]—A’alKoho], (Ger.). See A. alcohol, A. alcohol bromide, etc—A. amine. See ALLYL A MINE. and ethyl oxide. See Allyl ethyl ether.— A. and glyceryl oxide. See TRI ALLYL IN.—A. and hydrogen sulphate. Fr., sulfate d'allyle et d'hydrogène, Acid a. sulphate. See A. sulphate. nd hydrogen sulphide. Fr., sulfure CU et @hydro- See A. mercaptan.—A. and methyl oxide. See Allyl- See Allyl phenyl ether.— gene. methyl ether.—A. and phenyl oxide.. Fr., allyl-aniline. Ger., Allyl anilin. It., all i lan i lin a. Aniline in which a, replaces hydrogen: N(C, H, (C,H,)H = CyH,,N. {B, 2]—A. arsenide. Fr., arséniure d'allyle. Ger., Alylarsenitir, See TETRALLYLARSONIVM.—A’äther (Ger.). See A. ether.— At i i thy lather, A’iithyloxyd (Ger.). See Allyl ethyl ether—. Fr., allyl-benzine. Ger., Allyl benzol. It., allilbenzina. Beta phenyl propylene. [B.] See PHENYL PROPYLENE.— A. borate. Fr., borate d’allyle. Ger., Allyl bor at, Borsäure-Allyl ester. It., bora to di allile. Sp., bora to de alilo. A liquid emitting pungent irritating vapors and having the composition (C,H5)5BOs. f. 3.]—A. bromide. Fr., bromure d'allyle. Ger., Allylbromür, Bromallyl. It.,bromuro di allile. Sp., bromuro dealilo. A liquid of ungent odor, having the composition C,H,Br = CH,: CH—CHÊBr. fe 3.) For the other bodies called bromides of a., see DIALLYL tetra bromide and TRIBROMHYDRIN. —. Fr., allyl carbamide. Ger., Allylearbamid. See Allylurea. — A. carb a mine. Fr., allyl-carb a mine. Ger., Allyl carb am in. A. isocyanide. |B, 3.) See A. cyanide.—A. carb imide. Fr., allyl-carb imide. Ger., Allyl carb imid. See A. pseudo cyanate,—A., carbonyl, and hydrogen sulphide. See Allyl thio carbonic acid.—A. carboxyl a mine. Fr., allyl-carboxyl a mine. Ger., Allyl carboxyl am in. See ‘A. pseudo cyanate.—A. chloride, Fr., chlorure d'allyle. Ger. Allylchloriir. It., cloruro di allile. Sp., cloruro de alilo. A liquid of pungent odor, boiling at 44°6° C., and having the composition C3HsCl = CH,: CH—CH,Cl. [B, 3.] — A. ehlorobromhydrin. Fr., allyl-chlorobromhydrine. Ger., Allylchlorbromhydrin. See CHLOROBROMHYDRIN.—Â*cyanamide. Fr., allyl-cyanamide. Ger., Allulcyanamid. _ Syn,: sinamine. A substance of the composition C,N,Hg= CN.NH.C,H,, or, according to Hofmann, C,Ny(NH.CyH5)g. obtainéd by the action of lead hydroxide upon ailylthiourea.” 1 15 a syrupy ania which, combined with water of crystallization (2C,- NH, + HO), forms prismatic crystals. It has a very bitter taste and a strong alkaline reaction, and po e es marked basic Proper ties, [B, 3, 4J—A. cyanide.’ Fr, cyanure d'allyle. Ger., Allylcyanür. It., cianuro diallile. Sp., cianuro de alilo. A eon nOune of_a. with cyanogen. A. isocyanide, allyl carb a mine, C,H,N = c —CH,.CH: CH,, is a mobile liquid, having an exceedingly penetrating jeudipermeneny disagreeable odor. [B,3.]—A. cyano carbonate.. cyano carbonate d'allyle. Ger., Cyan carbonsäure-Allyl ester. A body of the constitution CO(GN)—0.C,Hs = OsHgNOz. [B, 2]—A. cyano formate. Fr., cyano formate d'allyle.” Ger., Cyan a me is ensäure-Allyl ester. A colorle liquid, having an odor of mustard, formed by the decomposition of a. alcohol dicyanide. [B, 3.|—A. dibromide. Fr., dibromure d’allyle. Ger., Allyldibromär. \t., dibromuro di allile. Sp., dibromuro de alilo. See DIALLYL tetra bromide.—A. dichlorhydrin. Fr., allyl-dichlorhydrine. Ger., Allyldichlorhydrin. A. alcohol dichloride. [B, 2.] See DICHLORHYDRIN.—A’diethylearbinol. Fr., allyl-diéthyl-carbinol. Ger., Allyldiäthylcarbinol. A tertiary alcohol of the composition CgH,,0 = (CsHs)(CgH,)2.COH. [B, 3.]—A. dilodide. Fr., Giiodure d'alyle. Ger.’ Allyldijodür. See DIALLYL tetra iodide.—. Fr., allyl-diisopropyl-carbinol. Ger… Allyldiisopropylcarbinol. A tertiary alcohol of the composition CyoH200 = (CoHs)(GH*>cH,.COH. [B, 3.]—A’dimethylearbinol. Fr. allyl-diméthyl-carbinol, Ger., AUyldimethulcarbinol. À tertiary alcohol of the composition C,Hy,0 = (C,H5 (CHz)z.COH. {B.2.|-A’dipropylearblnol. Fr, allyl-dipropyl-carbinol, Ger. Alt yid i propyl carbinol. À tertiary alcohol of the composition CyoHag- 6 = (GIH, \CH,.CH.CH,),.COH, [B, 3.] —. A salt of allyldithiocarbamic acid.’ [B.]— A, dithiocarbamic acid. Fr., acide allyl-dithiocarbamique. Ger., AUyldithiocarbaminsäure. Syn,: sulphosinapic acid, allylsulphocarbamic (ally! thio carbamic) acid. A monobasic acid, known only through its salts, having the composition NH(C,Hg)—CS—S.H = C,HzNS,, [B, 3.|—Ave igsiinre (Ger.). Allyl acetic acid. [B,]—A‘e igsiure- ‘A ethyl ester (Ger.), Ethyl allyl acetate, [B.]— A'e igsäure- Ester (Ger). Allylacotie ether, [B Avester Ger.). A comnd a, ether; a Salt of a, [B.|—A. ether. Fr., éther allylique. or, Aliyldther, Allyl ester. It.,etere allilico. Any compound of a. O, no; 0%, not; 03, whole; Th, thin; Tin, the; U, like 00 in too; U*, blue; U3, lull; U*, full; US, urn; US, like ü (German). with a non-metallic element or an acid radicle; particularly the compound of a. with oxygen, or diallyl oxide, C,H,90 = CH,: CH- CH,—O—CH, —CH: CH, a liquid lighter than water, having an odor of horse-radish, contained in crude oil of garlic. [B, 2, 3.)—. Fr., allyl-éthyle. Ger., Alyläthyl. It., allil-etile. See AmyLENE—A’ethyl ether. Fr, éther (ou oxyde) allyl-éthylique. Ger., AUyläthyläther, Allyläthyloxyd. It, etere (0 o ido allil-etiléco)" À liquid of the constitution C,H,—O—C,H, = CsHy00. [B, 3, 4.]-A'ethylic. Fr., allyléthylique. noth a. ethyl. [B.]—A’ethylic oxide, A’ethyl oxide.” See A’ethyl ether—‘eugenol. ‘ Fr., allyl-eugénol. Ger.… Allyl eugenol. A liquid having the composition Cy9H, 507 =.C;H5(O.CH,3)- (C,Hy). [B, 2]—A. formate. Fr., formiate d’allyle. Ger., Ametsensäure-Allyl ester. It., form i a to di allile. A liquid of Bungent odor resembling that of mustard, having the composition C,H,02 = CHO.OC:Hg. tp. 3.1 (Ger.), Aliylurea. fafa. hydrate. Fr. liydrate d’allyle. Ger, Allythydrat. It, idrato diallile. Sp., hidrato de alilo, A. alcohol —A. hydride. Fr., hydrure @aliyle. Ger., Allylhydriir, It, idruro di allile. Proylene. [B, 2, 4.J—A. hydrosulphide. See A. mercaptan.—A. aide. kr, todure d'ailyle. Ger, Allyljodür. It., ioduro di aldile. Sp., ioduro de alilo. A liquid of pungent garlicky odor having the constitution C,H,1 = CH,: CH—CFLI, [B.3.] For the so called diiodide of a., See DIALLYL tetra iodide, —A. iododichloride. Fr., iododichlorure d'allyle. Ger., Allyljodiirdichloriir. See IoDODICHLORHYDRIN.—A. isocyanate. Fr., isocyanate d’allyle. Ger., Allyl i so cyan at, Isocyanstiure-Aliylester, It, is ocean a to di allile. See A. pseudo cyanate,—A. isocyanide. cyanure dallyle. Ger., Allylisocyanir. It, isocianwro di allite, Sp., isocianuro de alilo. See A. cyanide.—A. isosulphocyanate, A. isosulphocyanide, A. i so thiocyanate. —Fr., i so sulfo cyan ure (ou i so sulfo cyanate ou i so thiocyanate) d'allyle. Ger., Allyl i so sulfo cyanür, Allyl sulfo cyan at, Allyl thio cyan at, It., isosolfocianuro (0 i so sol foci an a to) di allie, See A. pseudo thiocyanate, A’jodiir Ger). See A. iodide.—A'jodiirdichloriir (Ger.). See A. iododichloride—A’malonic acid. Fr., acide allyl-malonique. Ger., Alylmalonsäure. It., acido allil-malonico. A dibasic acid, isomeric with hydromuconic acid, having the constitution CaHsO4 = )H —(CO.OH),, of malonic acid in which a. replaces hydro gen. ([B,4.J—A. mercaptan. Fr., allyl-mercaptan. Ger., Allyl mercaptan, _A liquid of ethereal garlicky odor having the compo tion C,H,-SH, or that of a. alcohol in which sulphur replaces oxygen. [B, 3, 4.]—A’mercaptide. Fr., allyl-mercaptide. Get. Allylmercaptid. A compound of allyl mercaptan with a metal, of the general formula (CaHs-ShR, where R is a radicle of the quantivalence of n; an allylate in which sulphur replaces oxygen. [B.]—. ‘Fr, allyl-méthyle, Ger., Allyl methyl. It, allil-me' ile. Sp., alil-metilo. A radicle compounded of a. and meth normal butylene. BJ See BuTYLENE.—A’methyl ether. éther (ou oxyde) allyl-méthylique. methyloxyd. It., etere (0 o ido) allil-metilico. A colorle liquid of the constitution C,H,O = CH,: CH—CH,—O—CH,, formed by the action of a. iodide upon sodiuin methyl [B,4.]—A>’methyiic. Fr. allykméthylique, It., allikmetilico. Pertaining to or consisting of a. and methyl. (BJ—A vin ethylic oxide, A’methyl oxide. See A’methyl ether, —. Fr, euyl-métialpropylcarbinol. Ger., Allyl methyl propyl carbinol. A tertiary alcohol of the composition CH 1,0 = (C3H,)- (CH,\CsH)C01L, [B, 8-74. mono bromide. Fr" monobromure d’allyle. Ger.,’ Allylmonobromiir. It. monobromuro di allile. Sp., monobromuro de alilo, See A. bromide.—A. monochloride.’ Fr, monochlorure d'allyle. Ger., Allytmonochlortir, It, monocloruro di alle. Sp, monocloruro de alilo. See A. chloride. — A. mono iodide. Fr., monoiodure d'allyl Ger., Allylmonjodür. It., monoïoduro di allile, See A. iodide. A. mustard-oil. Ger., Allylsenfôl. See A. pseudo thiocyanate.— A. nitrate. Fr, azotate dallyle. Ger, Allylnitrat, Salpetersäure-Allyl ester. It. nitrato di altile. Sp, nitrato de alilo. A mobile liquid of pungent odor having the constitution C,H,.NOg. [B, 3.|—A. oxalate.” Fr., oxalate d’allyle. Ger., AUyloxalat, Oxalsäure-Allyl ester. It, o alato di allile. Sp. oxalato de dlilo. An ex liquid, having an odor of mustard, of the composition CsH1004 = C,0g.Og(C,Hg),. [B, 2, 3.]—. Fr, oxyde d'allyle: Ger., Aüploryd: 'It., o ido di allile, Sp., dwido de aldo. See À. ether.—A’oxy butyric acid, Fr, acide a lyt-oxybutyrique. Ger., Allylocybuttersiure. It., acido all i to i but i rico. A monobasic acid having the constitution C,H,,0, = CH,.CH(OH).CH- (C,H5) — CO.OH, or that of hydroxy butyric acid in which a. replaces hydrogen. IB 4.J—A’phenol. Fr, allyl-phénol. Ger., Allyl phenol. Ît., allilfenoto. Syn.: anol. A substance forming laminar crystals of the constitution CpH,,0 = CH (OHXCgHg), prepared by the action of potash upon anisic aldehyde. [B, 158.] Containing both a. and Fr. Ger., Allyl methyläther, Allyi- A phenyl ether. Fry éther (ou oxyde) ally-phenyl i que. "Ger., Ally henyloxyd. It., etere (0 o ido) allil-fen it: phenyläther. Alylp ico. A rle , strongly refracting liquid, of the same density as water, formed by the action of sodium phenyl ate upon a. bromide, and having the composition CpH,90 = CyH,.O0 — CHg, isomeric with allyl phenol. [B, 2.]—A’phenylic. Fr., dllyl-phénylique. It, allil-fenilico, Containing both a. and phenyl. [B,|—A’ phenylie oxide, A’phenyl oxide. See A'phenyl éther.—A’ piperidine. Fr, allyl-pipéridine, Ger., Allyl pipe rid in. À liquid, boiling at 140° C., having the composition CaHy5N = CsH,oN.C,Hg.{B, A. pseudo cyanate. Fr., pseudo cyanate d'allyle. Ger. Alylpseudocyanat, Pseudo cyansäure-Allyl ester. Syn.: allyl carboxyl a mine, a. isocyanate. An oily liquid, of pungent irritating odor, formed by the action of poto ium udo cyanate upon a. iodide, and having the constitution C,H,NO = CH, + CH CH, N10: 0. [B, 4.]-A. pseudosulphoeyanate, A. pseudo thiocyanate. Fr.) pseudo sulfo cyanate (ou pscudothiocyanate) d'allyle.Ger.… Alu pseudo sulfo cyan at, Allyl pseudo thio cyan at. Syn.: a. i so thiocyanate, a. isosulphocyanate, a. mustard-oil. position C,H,NS = CH,: CH.CH, — N: C composition of myronic A’thiocarbamide. Fr, allyl-thiocarbamide. Ger., Alylthiocarbamid. See A°thiourea,—A’thio carb imide. Fr, allyl-thio carb imide. Ger., Allyl thio carb imid. See A. pseudo thiocyanate. —A*thio carbonate. Fr., allyl-thio carbonate. Ger., Allyl thio carbon at. A salt of allyl thio carbonic acid. [B.]—A°thio carbonic acid. Fr., acide allyl-thio carbon i que. Ger., Ay bier E Dy onsäure. A substance, occurring under the form of yellow. acicular crystals, having the properties of a monohasic acid, and the formula C,H,S.0. = (CsH,)S — CO— SH, or that of thio carbonic acid in which a. replaces hydrogen. [B, 2]—A. thiocyanate. Fr., thiocyanate dallyle. Ger., Allyl thio cyan at, coven ure-Allyl ester. A substance of the composition C,H,SN=N=C—8— CH,.CH: CHg, isomeric with a. pseudo thiocyanate, and readily convertible into the latter. It is a colorle , highly refracting, oily liquid, having an odor resembling at once that of garlic and that of hydrocyanic acid. It produces headache, nausea, and nervous disorders when inhaled. [B, 2, 3.|—A. thioether, Fr., allyl-thioéther. Ger., Allylthiodther. See A. sulphide.—A’thio harns toff (Ger.). A thiourea. [B.]—A’thiourea. Fr., allyl-thiourée. Ger., Alylthicharnstoff. Syn.: sinamine [Will], mustard-oil ammonia, allyl thio carb a mine. A base, formed by the action of ammonia on oil of mustard, and having the constitution of thiourea in which a. replaces an atom of hydrogen; CllaNaS — HaN CS —NH(Cpiy t forms crystals moderately soluble in water, readily soluble in alcohol. Given internally, it produces cardiac palpitation and insomnia, and is excret by the urine as ammonium thiocyanate. [Wöhler and Frerichs (B, 3).]—A. tri bromide. Fr., tribromure @allyle. Ger., Allyltribromür. It., tribromuro di allile. Sp., tribromuro de alilo. See TRIBROMHYDRIN.—A. trichloride. Fr., trichlorure d’allyle. Ger., Allyltrichlorär. It, tricloruro di allite, Sp, tricloruro de alilo. See TRICHLORHYDRIN.—A’urea. Fr., alipi-urée. Ger., Allyl harns toff. It., allil-urea. A substance forming prismatic crystals readily soluble in water, having the constitution C,H£N,0 = NH, — CO —. being that of urea in which a, replaces 1 atom of hydrogen. {B, 3.) Cf. DIALLYL urea.— A’xanthic acid. Fr., acide allyl-xanthique. See A’thio carbonic acid.—A me is ens aures A. (Ger.). See formate.—Borsaures A. Ger.). See A. borate—Cyan a me is ens aures A. (Ger.). See À. cyano formate —E lgsaures A. (Ger.). eyansaures A.(Ger.). ° See A. pseudo cyanate.—Isothiocy saures A. (Ger.). See A. Meena nOciCagee Oxalsaures A (Ger.). See A. oxala Pseudocyausaures A. (Ger.). See pseudo cyanate.—Pseudo thio cyans aures A, (Ger.). See A. pse dothipoyana ter Salas Lars opr ed| A. (Ger.). See A. nitrate. Schwefela’ Ger.). A. sulphide.—Schwefeleyana’ (Ger.). thiocyanate —Schwefelsaures A. (Ger.). See A. sulphate.